WebbExplanation: [NiCl4]2- : Nickel (Ni) in the complex [NiCl 4] 2- is in a +2 oxidation state. Hence the electronic configuration is [Ar]3d8. Out of 8 3d electrons, 6 are paired and two are unpaired. As Chlorine is a weak field ligand, it is not able to pair the electrons in Nickel and thus d orbitals of Ni do not participate in hybridization. Webb$\begingroup$ On a somewhat unrelated note: I find it interesting that this effect is also present in d9 transition metals. The Jahn-Teller effect is like if this orbital energy inversion happened but not quite all the way... like it …
What is the hybridization for [NiCN4]2 - BYJU
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[Ni(CO)4 has a tetrahedral geometry whereas [Ni(CN)4]4– has …
WebbNi is in the +2 oxidation state i.e., in d 8 configuration.. There are 4 CN − ions. Thus, it can either have a tetrahedral geometry or square planar geometry. Since CN − ion is a strong field ligand, it causes the pairing of unpaired 3d electrons.. It now undergoes dsp 2 hybridization. Since all electrons are paired, it is diamagnetic. Webb15 mars 2024 · Both [Ni (CO)4] and [Ni (CN)4]2- are diamagnetic. The hybridisations of nickel in these complexes respectively, are (a) sp3, sp3 (b) sp3, dsp2 (c) dsp2, sp3 (d) dsp2, dsp2 transition elements coordination compounds jee jee mains 1 Answer +1 vote answered Mar 15, 2024 by Ankitk (74.5k points) selected Mar 15, 2024 by Vikash … WebbNi is in the +2 oxidation state i.e., in d 8 configuration.. d 8 Configuration . There are 4 CN − ions. Thus, it can either have a tetrahedral geometry or square planar geometry. Since CN − ion is a strong field ligand, it causes the pairing of unpaired 3d electrons.. It now undergoes dsp 2 hybridization. Since all electrons are paired, it is diamagnetic. britishop pattaya thailand